Molecular Alignment on Demand

Symmetric molecules experience enhanced, unidirectional field-free orientation via a single resonant pulse that selectively couples an initial rotational state [latex]|J_0K_0M_0\rangle[/latex] to an adjacent state [latex]|J_0+1K_0M_0\rangle[/latex], a process demonstrated through a two-state excitation model where the angle [latex]\theta[/latex] between the molecular axis and laser polarization dictates the resulting periodic evolution and angular distribution of the rotational wave packet.

Researchers have devised a method for precisely controlling the orientation of molecules in space using only carefully shaped light pulses.